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What is Corrosion

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What is Corrosion?

Corrosion can be defined as the destructive attack of a metal through interaction with its environment.

             

              

DRIVING FORCE FOR CORROSION.

 

In order to answer the question What is Corrosion? and to know more about corrosion, is necessary to understand how corrosion works and why metals are affected by corrosion.

 

Metals used in the construction, e.g. steel, stainless steel grades, copper alloys, are subject to corrosion, this is due to the high energy content of the elements in metallic form.

 

In nature, most metals are found in chemical combination with other elements; these metallic ores are refined by man and formed into metals and alloys.

 

As the energy content of the metals and alloys is higher than that of their ores, chemical re-combination of the metals to form ore like compounds, i.e. the corrosion, is a natural process.

             

MORE ABOUT CORROSION, FUNDAMENTAL MECHANISM OF ATTACK.

 

Corrosion of metals takes place through the action of the electrochemical cell. Although this single mechanism is responsible, the corrosion can take many forms.

 

              

The Electrochemical Cell.

 

As in all chemical reactions, corrosion reactions occur through an exchange of electrons.

 

In electrochemical reactions, the electrons are produced by a chemical reaction in one area, the anode area, travel through a metallic path and are consumed through a different chemical reaction in another area, the cathode.

 

Typical Reactions.

 

The generic chemical reaction for this metal loss at anodic sites is:

              

M ---> M+ + e-

              

where:

M = uncharged metal atom at the metal surface

M+ = positively charged metal ion in the electrolyte

e- = electron that remains in the metal

              

              

This type of chemical reaction is called metal oxidation even though it does not directly involve oxygen but only results in an increase in positive charge on the atom undergoing oxidation.

More than one electron can be lost in the reaction as in the case of iron where the most common anodic reaction is:

              

Fe ---> Fe2+ + 2e-

where:

              

Fe = metallic iron

              

Fe2+= ferrous ion that carries a double positive charge

 

Cathodic Reactions.

 

The electrons that are produced at anodic sites are consumed at cathodic sites. The type of chemical reactions that consume electrons are called reduction:

 

One of the most common cathodic reaction is the reduction of oxygen:

              

O2 + 4e- + 4H2O ---> 4OH-

 

 

 

 

iron corrosion, mechanism of iron corrosion

 

To sum up:

 

- Corrosion is a process by which a metal is deteriorated

 

- An electrolyte is necessary in order to have corrosion on a metal

 

see also:

 

What is Rust?

 

Corrosion Types

 

Metal Rust Remover

 

What is the best Rust Remover?

 

What causes rust?

 

Galvanic Corrosion